According to eyewitness reports, the chemical burned straight through a foot of concrete and three feet of gravel while simultaneously releasing a deadly cloud of gas containing a cocktail of chlorine trifluoride, hydrogen fluoride, chlorine and hydrogen chloride that corroded every surface it came into contact with. The collection is called Things I Wont Work With and is a hair-raising categorization of substances that Dr. Lowe in particular refuses to go anywhere near. The elongated Cl-F axial bonds are consistent with hypervalent bonding. But another nice thing about this paper is the way some parts of it are written, in a style which was a bit formal and archaic even for 1943. The real question is whether it's all worth using. Together, these occasional entries make up the most entertaining and terrifying science-related blog on the internet. It is apparently about the most vigorous fluorinating agent known, and is much more difficult to handle than fluorine gas. You may observe the mild reactivity of this gentle substance as it encounters various common laboratory materials, and draw your own conclusions. Oh, and in the process, it also released hot, deadly clouds of hydrofluoric acid that corroded everything in its path. Chlorine trifluoride is a chemical which should only be handled by professionals. AAAS is a partner of HINARI, AGORA, OARE, CHORUS, CLOCKSS, CrossRef and COUNTER. The substance is so highly reactive that famously unreactive elements like platinum, osmium and iridium will begin to corrode when they come into contact with it. I have not encountered this fine substance myself, but reading up on its properties immediately gives it a spot on my no way, no how list. Engagements are likely to take place at pretty extreme ranges, and ships will probably have decent avoidance maneuvers. Use Raster Layer as a Mask over a polygon in QGIS, How small stars help with planet formation. Not really. or w/e i introduce myself as. yielded a mixture of sodium chloride and sodium azide. Chlorine Trifluoride-producing microorganisms. It will not only set water on fire, but water makes it explode. Contrive for them to "find" semi-destroyed plans for a weapon prototype in a way that they can't help but believe is real. There's a small leak in a storage unit, and chlorine trifluoride reaches a nearby surface, immediately starting a toxic reaction that will kill many people on the ship because they're trapped in space and have nowhere to hide. It burned its way through a foot of concrete floor and chewed up another meter of sand and gravel beneath, completing a day that Im sure no one involved ever forgot. CIF3 is an effective oxidizer, one that's arguably too effective. If it's not perfectly treated, then kaboom goes the vessel. Chlorine trifluoride is typically used in nuclear fuel processing, as its converts uranium into gaseous hexafluoride uranium. 13. Further, there is really little one can do to put out the fires it causes directly other than to let them burn off. Of all the dangerous chemical gases, chlorine trifluoride is known to be the most flammable. Manage your stress with a perfect tune backed by science. What ClF3 can do to an enemy spaceship that a good old atomic bomb can't do? Derek Lowes commentary on drug discovery and the pharma industry. They isolated the compound chlorine trifluoride (ClF3), which was liquid (check!) It also has a nice fat density, about 1.81 at room temperature. Copyright 20122023 flippinOptimist. He has curated a horrific collection of nasty poisonous reagents from his own field of organic chemistry, alongside a hellish collection selected from other specializations. Frankly, the more difficult it is (so long as some future tech can automate the process) the more interesting it would be in a book. How to intersect two lines that are not touching. four days 10 Peter Equal to 20. It reacts with water to form chlorine and hydrofluoric acid with release of heat. Scientists have recommended the RTS,S vaccine for children in sub-Saharan Africa and other high-risk areas to prevent one of the worlds oldest and deadliest infectious diseases. . It is known to ignite sand, asbestos, glass, and even ashes of substances that have already burned in oxygen. That process, I should add, would necessarily have been accompanied by copious amounts of horribly toxic and corrosive by-products: its bad enough when your reagent ignites wet sand, but the clouds of hot hydrofluoric acid are your special door prize if youre foolhardy enough to hang around and watch the fireworks. Pure fluorine could put the body on self-ignited fire. Kecuali dinyatakan lain, data di atas berlaku pada temperatur dan tekanan standar (25 C [77 F], 100 kPa). It is used in rocket fuels and in processing nuclear . It only takes a minute to sign up. It reacts with water to form chlorine and hydrofluoric acid with release of heat. If you've seen a shooting star on a recent stargazing jaunt, you've spotted the very beginning of the Orionids meteor shower. Watch for the fireworks. Chlorine trifluoride is such an effective oxidizer that it can even potentially set fire to things that have seemingly already been burned up, like ash or spent charcoal. Gases can cause rapid suffocation because of oxygen deficiency; store . But not here. Chlorine Trifluoride is a colorless gas or a white solid with a sweet, suffocating odor. in tempus justo mattis vel, tristique porta. Lowe lists with incredulity all the substances he managed to react with it: ammonia (vigorous, this at 100K), water ice (explosion, natch), chlorine (violent explosion, so he added it more slowly the second time), red phosphorus (not good), bromine fluoride, chlorine trifluoride (say what? It sets fire to glass, to rubber, to sand, to iron, copper, aluminium you name it. What you're trying to do is to create CIF3 atmosphere to burn enemies, but venting it to space would vent it like any other atmosphere. As an example of the kind of devastation chlorine trifluoride can have, you only need to consider what happened when almost a ton of this stuff was accidentally spilled inside of a warehouse in the 1950s. Chlorine trifluoride appears as a colorless gas or green liquid with a pungent odor. This will be accomplished by mounting your copper vessel in a magnetically accelerated slug or self-propelled missile. Comments are not for extended discussion; this conversation has been. Theres a report from the early 1950s (in this PDF) of a one-ton spill of the stuff. Quoting John Drury Clark: It is, of course, extremely toxic, but that's the least of the problem. It is not. Cesium2. Oxygen or ozone shells would do same thing, although not as intense. The same isn't true in a war zone, where speed is of the essence. One of the main uses of ClF3 is to produce uranium hexafluoride, UF6, as part of nuclear fuel processing and reprocessing, by the fluorination of uranium metal: The compound can also dissociate under the scheme: In the semiconductor industry, chlorine trifluoride is used to clean chemical vapour deposition chambers. What does chlorine trifluoride do to the body? Have fun. The only known way to store chlorine trifluoride safely, which we use in the loosest possible sense, is to put it inside of a sealed containers made of steel, iron, nickel or copper which are able to contain the chemical safely if theyre first treated with flourine gas. . It burned its way through a foot of concrete floor and chewed up another meter of sand and gravel beneath, completing a day that I'm sure . Chemical Properties. 2.1.2 Odor 2.1.3 2.1,11 Chlorine trifluoride odor has been re~orted as both sweet ~nd pungent, similar to chlorine or mustard. Chlorine trifluoride is prepared by the reactionCl2(g) + 3F2(g) 2ClF3(g). [20][17] There is exactly one known fire control/suppression method capable of dealing with ClF3 flooding the fire with nitrogen or noble gases such as argon. Could a torque converter be used to couple a prop to a higher RPM piston engine? . The extremely rare blood type is shared by only a handful of people on Earth. @StianYttervik, while true that a portion of my answer assumes the simple mixing of chemicals, it doesn't change the fact that the creation of ClF3 is nothing more than a process. The compound is primarily of interest in and etching operations in the semiconductor industry, in nuclear reactor fuel processing, as a . Click the who am i page to see a list a shit ill do for strangers. In one particular industrial accident, a spill of 900kg of ClF3 burned through 30cm of concrete and 90cm of gravel beneath. Or it's just banned by acting rules of engagement. Barring that, the area must simply be kept cool until the reaction ceases. This will be determined by the number of atoms and lone pairs attached to the central atom.If you are trying to find the electron geometry for ClF3 we would expect it to be Trigonal bipyramidal.Helpful Resources: How to Draw Lewis Structures: https://youtu.be/1ZlnzyHahvo Molecular Geometry and VSEPR Explained: https://youtu.be/Moj85zwdULg Molecular Geo App: https://phet.colorado.edu/sims/html/molecule-shapes/latest/molecule-shapes_en.htmlGet more chemistry help at http://www.breslyn.orgDrawing/writing done in InkScape. [14] This structure agrees with the prediction of VSEPR theory, which predicts lone pairs of electrons as occupying two equatorial positions of a hypothetic trigonal bipyramid. Derek Lowes commentary on drug discovery and the pharma industry. ), tetrafluorohydrazine (how on Earth. Are Electric Highways the Way of the Future? Chlorine trifluoride has been investigated as a high-performance storable oxidizer in rocket propellant systems. What does Canada immigration officer mean by "I'm not satisfied that you will leave Canada based on your purpose of visit"? Sensory loss has a profound effect on millions of peoples everyday lives. I am reviewing a very bad paper - do I have to be nice? That process, I should add, would necessarily have been accompanied by copious amounts of horribly toxic and corrosive by-products: its bad enough when your reagent ignites wet sand, but the clouds of hot hydrofluoric acid are your special door prize if youre foolhardy enough to hang around and watch the fireworks.. Chlorine Trifluoride (ClF3) SC (Semiconductor) is a nearly colorless gas with an irritating odor similar to chlorine or mustard with an extremely low odor threshold. . Say hi any time. We have Plexiglas, a rubber glove, clean leather, not-so-clean leather, a gas mask, a piece of wood, and a wet glove. 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