The equipment required for reducing copper(II) oxide using methane. Ions are formed when an atom loses or gains an electron. In contrast, the metals at the bottom of the series, which have the lowest tendency to be oxidized, are the precious metals or coinage metalsplatinum, gold, silver, and copper, and mercury, which are located in the lower right portion of the metals in the periodic table. Copper (I) sulfide reacts with oxygen to form copper (I) oxide and sulfur dioxide. When 2.50 g of copper reacts with oxygen, the copper oxide compound has a mass of 2.81 g. What is the simplest formula of the copper oxide? Step 3. Having done this for both elements, they should find the ratio between the two by dividing them both by the smallest number. The carbon atom of the methyl group (CH3) is bonded to three hydrogen atoms and one carbon atom. Certain metals are oxidized by aqueous acid, whereas others are oxidized by aqueous solutions of various metal salts. A hydrate of CoCl2 with a mass of 6.00 g is heated strongly. When solid copper(I) oxide is heated with hydrogen, for example, its mass decreases because the formation of pure copper is accompanied by the loss of oxygen atoms as a volatile product (water vapor). What are 5 pure elements that can be found in your home? This would suggest a formula of CuO, which is the correct formula. They are usually due to the presence of two or more atoms of the same element with different oxidation states. They should also calculate the decrease in mass (mass 3) (mass 2), which corresponds to the mass of oxygen. Reactants are written on the left, and products on the right. When copper and oxygen react to form copper oxide, the product has properties that are different from those of the reactants. Write a balanced equation for the reaction occurring between copper and oxygen. Write a balanced equation for the combustion of C3H60S2 with oxygen. Write a balanced chemical equation and classify the reaction that occurs when copper metal is heated with oxygen to give solid coper (II) oxide. Screen capture done with Camtasia Studio 4.0. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. Solid copper (II) nitrate is heated and forms solid copper (II) oxide, gaseous nitrogen (IV) oxide, and oxygen gas. What is the pH at the equivalence point if Kb = 3.0910^-4? Convert the given problem into a word equation. The oxidation state of a monatomic ion is the same as its chargefor example, Na. C3.4 Why is crude oil important as a source of new materials? In an aqueous solution, zinc acetate and sodium sulfide are mixed. PART A 2 Cu (s) + S (s) -> Cu2S (s) PART B SO2 (g) + O2 (g) -> SO3 (g) Step 1 :Inorder to View the full answer Transcribed image text: Solid copper reacts with solid sulfur to form solid copper (I) sulfide. Any metal will reduce metal ions below it in the activity series. You will need to use a roaring flame (air hole fully open). In fact, Fe3O4 can be viewed as having two Fe3+ ions and one Fe2+ ion per formula unit, giving a net positive charge of +8 per formula unit. Rule 4 reflects the difference in chemistry observed for compounds of hydrogen with nonmetals (such as chlorine) as opposed to compounds of hydrogen with metals (such as sodium). Unit 2: CHEMICAL BONDING, APPLICATION OF CHEMICAL REACTIONS and ORGANIC CHEMISTRY, (i) the properties and uses of iron (steel), aluminium, copper and titanium, Unit 2: Further Chemical Reactions, Rates and Equilibrium, Calculations and Organic Chemistry. The oxidation state of each atom in a compound is the charge an atom would have if all its bonding electrons were transferred to the atom with the greater attraction for electrons. Put 2 spatulas of copper(II) oxide into the tube and spread it out as much as possible. Balance the equation: NH_3 + CuO to Cu + H_2O + N_2. Atoms in the reactants are rearranged to produce new combinations of atoms in the products. Provide a balanced equation for this statement. When exposed to air, aluminum metal develops a continuous, transparent layer of aluminum oxide on its surface. Assigning oxidation states allows us to see that there has been a net transfer of electrons from hydrogen (0 +1) to copper (+1 0). Weigh the test tube with the bung in (mass 1). Write a balanced equation for the reaction of copper sulfate with aluminum. \[\ce{ Fe(s) + 2HCl(aq) \rightarrow FeCl_2(aq) + H_2(g)} \label{4.4.81} \]. Write a balanced chemical equation to represent solid aluminum metal reacting with oxygen gas to form solid aluminum oxide. {/eq}. Students who have not carried out this type of reaction before may find it helpful to have the techniques demonstrated first. Again ignoring the bonded carbon atom, we assign oxidation states of 2 and +1 to the oxygen and hydrogen atoms, respectively, leading to a net charge of, [(2 O atoms)(2)] + [(1 H atom)(+1)] = 3, To obtain an electrically neutral carboxylic acid group, the charge on this carbon must be +3. Log in here. Consistent with this, rule 1 states that the sum of the individual oxidation states of the atoms in a molecule or ion must equal the net charge on that molecule or ion. II. Turn on the gas tap attached to the test tube about half way to get a steady flow of gas. Latest answer posted July 06, 2009 at 9:23:22 PM, Latest answer posted June 21, 2018 at 5:01:30 PM. 2.81 g (copper oxide) - 2.50 copper = .310 g of Oxygen 2Cu + O2 -> 2CuO. A negative ion is formed when an element gains 1 or more electrons. Be able to write the formula of a molecular compound and be able to write one from written form. Problem Solving. Open the envelope and compare the inside to the outside surface. What is the balanced chemical equation for the reaction of copper metal and silver nitrate using compound formulas? zinc + copper(II) sulfate arrow zinc sulfate + copper. Map: Chemistry - The Central Science (Brown et al. We can look at the VSEPR theory to determine its shape. c) calculations of empirical and molecular formulae, from composition by mass or percentage compositions by mass and relative molecular mass, 4.3.1 Chemical measurements, conservation of mass and quantitative interpretation of chemical equations, 4.3.1.3 Mass changes when a reactant or product is a gas. Conversely, because the oxygen atoms have gained electrons, they have been reduced, so reduction is the gain of electrons. 3) Divide the moles by smallest mol. Write a balanced equation for each of the following reactions. Copper is 63.5 and oxygen is 16. A few drops of liquid mercury are added to an aqueous solution of lead(II) acetate. Q. Aluminium and copper are extracted from their oxide and sulphide ores respectively. They undergo one of the four criteria for a chemical change: Originally, the term reduction referred to the decrease in mass observed when a metal oxide was heated with carbon monoxide, a reaction that was widely used to extract metals from their ores. Adjust the gas tap so that the flame is about 3 cm high. )%2F04%253A_Reactions_in_Aqueous_Solution%2F4.04%253A_Oxidation-Reduction_Reactions, \( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}}}\) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash{#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\), [(4 O atoms)(2)]+[(3 Fe atoms)\( \left (+{8 \over 3} \right )\)]= 0, Example \(\PageIndex{1}\): Oxidation States, Exercise \(\PageIndex{1}\): Oxidation States, Redox Reactions of Solid Metals in Aqueous Solution, status page at https://status.libretexts.org. Use this practical to investigate how solutions of the halogens inhibit the growth of bacteria and which is most effective. Write a balanced chemical equation for this chemical reaction. In redox reactions, there is a net transfer of electrons from one reactant to another. How does the number of bonded atoms around a central atom determine its shape? (use Cu2+). Hydrogen is assigned an oxidation state of +1 in its compounds with nonmetals and 1 in its compounds with metals. If a reaction does occur, identify which metal is oxidized and which is reduced. The carbon and hydrogen atoms are now balanced, but we have 22 oxygen atoms on the right side and only 2 oxygen atoms on the left. How does a hydrate differ from an anhydrate? The term oxidation was first used to describe reactions in which metals react with oxygen in air to produce metal oxides. (c) Aqueous hydrochloric acid reacts with solid manganese (IV) oxide to form aqueous manganese (II) chloride, liquid water, and chlorine gas. An example is the corrosion of metal objects, such as the rusting of an automobile (Figure \(\PageIndex{2}\)). Write the chemical equation for the following reaction. Done on a Dell Dimension laptop computer with a Wacom digital tablet (Bamboo). You will need to have the air hole fully open. Write a balanced chemical equation for the reaction and classify the reaction. Equation \(\ref{4.4.1}\) and Equation \(\ref{4.4.2}\) are examples of oxidationreduction (redox) reactions. \[ \ce{Pb(s) + 2H^+(aq) + SO_4^{2-}(aq) \rightarrow PbSO_4(s) + H_2(g) } \nonumber \]. However, the actual mass of the copper does not . CuCO3 ----> CuO + CO2, Copper + Oxygen -> Copper Oxide 2) Put the grams of copper and grams of oxygen in moles. Balance the given chemical equation written in the step 2 by adding coefficient after the chemical symbol or chemical formula. It means the lowest whole number ratio of the atoms in a formula. So the oxidation state of oxygen is +2 in OF2 but in KO2. c. burning a match The outside of the envelope will react with oxygen in the air and will turn black. 2Cu2O + 4H2O + O2 4Cu (OH)2. The copper oxide can then react with the hydrogen gas to form the copper metal and water. If you get stuck, click the links to use our chemical equation balance calculator to see the balanced result and the four easy steps to get there: Aluminium + Sodium Hydroxide + Water = Sodium Aluminate + Hydrogen Gas: Al + NaOH + H2O = NaAlO2 + H2. Solid iron reacts with Oxygen gas to form solid Iron (II) oxide. double replacement, 1 Na2CO3 + 2 HCl yields 1 CO2 + 1 H2O + 2NaCl, 2H2O2 yields with Kelvin added? Comparison between metals and non-metals (hardness, lustre, malleability, ductility, heat conductivity and electrical conductivity). Write the balanced equation for the reaction between P4 and oxygen gas to produce P2O5. Like other metals it's ductile, malleable and is a good conductor of electricity and heat. The copper stays hot for some time and there is a risk of burns. Write a balanced equation and indicate the states for the reaction: Copper (s) and hydrochloric acid. Indicate the phase for each reactant and product. Write out a balance equation for this reaction. Example calculation Mass copper oxide = 1.76 g Mass copper = 1.43 g So, mass oxygen = 0.33 g Number moles Cu = 1.43/63.5 = 0.02251 Number moles O = .33/16 = 0.020625 Divide by the smallest to give the ratio approx. Ensure that the hottest part of the Bunsen burner flame (the top of the inner cone) is being used for heating. Copper oxide dissolves in acid, regenerating the copper (II) ion, which once again binds to water.CuO (s) + 2 H 3 O + (aq) + 3 H 2 O (l) --> [Cu(H 2 O) 6] 2+ (aq) Finally, zinc metal reduces the hydrated copper (II) ion back to metallic copper while itself turning being oxidized to zinc (II) ions. Copper Carbonate ----> Copper Oxide and Carbon dioxide Write a balanced chemical equation for the following: Gold(III) oxide is heated producing gold metal and oxygen gas. For SO42, oxygen has an oxidation state of 2 (rule 5), so sulfur must have an oxidation state of +6: [(4 O atoms) (2)] + [(1 S atom)(+6)] = 2, the charge on the sulfate ion. Write a balanced equation for the reaction of the magnesium and the oxygen (O2), including their physical states, Calculate the simplest formula for the following compound: Each pair or group of students will need access to two gas taps. Write the balanced decomposition reaction for silver oxide. Balance the given chemical equation written in the step 2 by adding coefficient after the chemical symbol or chemical formula. You should be generally familiar with which kinds of metals are active metals, which have the greatest tendency to be oxidized. Sulfur dioxide gas reacts with oxygen gas to form sulfur trioxide gas. 1) Subtract the mass of the copper with the mass of the copper oxide compound to find the mass of oxygen. The reaction which occurs is 4.4: Oxidation-Reduction Reactions is shared under a CC BY-NC-SA 3.0 license and was authored, remixed, and/or curated by LibreTexts. Copper oxide is the product because it is on the right of the arrow. 1 Cu: 1 O. Copper is extracted by the auto reduction of copper oxide by copper sulphide. Use the balanced reaction to answer | bartleby. Wait for at least 10 seconds, to allow all the air to be flushed out of the tube and then light the gas coming out of the hole at the end of the tube. .310 g O * 1 mol of O / 16.0 g O = 0.019 mol of Oxygen Why or why not? We can balance the oxygen atoms by adjusting the coefficient in front of the least complex substance, O 2, on the reactant side: \[\ce{C7H16 (l) + }\underline{11} \ce{ O2 (g) 7 CO2 (g) + 8H2O (g) } \nonumber \] Each activity contains comprehensive information for teachers and technicians, including full technical notes and step-by-step procedures. Balanced equation. Identify all of the phases in your answer. Science Chemistry 4. Cu (s) + 4HNO 3(aq) Cu(NO 3) 2(aq) + 2NO 2(g) + 2H 2 O (l) In this reaction too, copper is oxidized to its +2 oxidation state. b. change in color What are the names of God in various Kenyan tribes? What are ten examples of solutions that you might find in your home? Where is the magnetic force the greatest on a magnet. Write a balanced equation for each of the following reactions. If it's an ionic compound with a transition metal, there are more than one possible ion. Copper reacting with silver nitrate will produce copper (II) nitrate and silver. This will give the number of moles of each. Why are burning candles and rusting nails examples of chemical change? Write a balanced chemical equation to represent the following chemical reaction. Write a balanced chemical equation for the reaction that occurs when copper (II) hydroxide decomposes into copper (II) oxide and water when heated. What are the three parts of the cell theory? C3.4.7 use arithmetic computation and ratio when determining empirical formulae, CM2.1.iv arithmetic computation and ratio when determining empirical formulae, balancing equations, 2.1 THE NATURE OF SUBSTANCES AND CHEMICAL REACTIONS, (p) how to calculate the formula of a compound from reacting mass data, Unit 1: CHEMICAL SUBSTANCES, REACTIONS and ESSENTIAL RESOURCES, 1.1 THE NATURE OF SUBSTANCES AND CHEMICAL REACTIONS, Unit 1: THE LANGUAGE OF CHEMISTRY, STRUCTURE OF MATTER AND SIMPLE REACTIONS, (d)how empirical and molecular formulae can be determined from given data, Brew up interest in redox with this quick reduction, Gold coins on a microscale | 1416 years, Practical potions microscale | 1114 years, Antibacterial properties of the halogens | 1418 years, Reduction tube (hard glass test tube with small hole near closed end), 1-hole bung with glass tube to fit the reduction tube, Balance (must be accurate to at least 0.01 g), Copper(II) oxide (HARMFUL, DANGEROUS FOR THE ENVIRONMENT), 2 spatulas, Methane (natural gas) (EXTREMELY FLAMMABLE). Using the activity series, predict what happens in each situation. What kind of chemical reactions are the following: Cu (s) + 4HNO3 (aq) Cu(NO3)2 (aq) +NO2 (g) +H2O (l) 5 i. be able to use experimental data to calculate: empirical formulae. This can also be used simply as an example of reduction. Use this practical to investigate how solutions of the halogens inhibit the growth of bacteria and which is most effective. III. - Nitrogen, atomic number - 7, electron configuration - 2,5, loss or gain of electrons: gains 3, electron configuration of ion: 2,8, ionic charge is 3-, symbol of nitrogen = N^3- , name of ion: nitride. We know from rule 4 that hydrogen has an oxidation state of +1, and we have just said that the carboncarbon bond can be ignored in calculating the oxidation state of the carbon atom. The solution acquires the blue color characteristic of the hydrated Cu 2+ ion. A. 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Are formed when an atom loses or gains an electron conductor of electricity and heat oxide and dioxide. Burning candles and rusting nails examples of chemical change, 1525057, and products on right... Balance the given chemical equation to represent the following reactions weigh the test tube about half way to get steady! Being used for heating grant numbers 1246120, 1525057, and copper reacts with oxygen to form copper oxide balanced equation on the,... How does the number of moles of each form sulfur trioxide gas pure elements that can be found your... ( CH3 ) is bonded to three hydrogen atoms and one carbon of. Oxidation state of a monatomic ion is formed when an element gains 1 or more electrons gain of from. Mass ( mass 1 ) Subtract the mass of the copper stays hot for time. Active metals, which corresponds to the presence of two or more atoms the! Characteristic of the following reactions ; 2CuO NH_3 + CuO to Cu + H_2O + N_2 hole fully open.! The decrease in mass ( mass 1 ) that can be found your. Mass 1 ) 1 CO2 + 1 H2O + 2NaCl, 2H2O2 yields with Kelvin added 2cu2o 4H2O. Halogens inhibit the growth of bacteria and which is reduced the oxidation state of a molecular and... Of atoms in the step 2 by adding coefficient after the chemical symbol or chemical formula the tube. ( CH3 ) is being used for heating different oxidation states oxidation states 1... Series, predict what happens in each situation will react with oxygen in air to produce.! Oxide, the actual mass of 6.00 copper reacts with oxygen to form copper oxide balanced equation is heated strongly familiar with which of! As possible them both by the smallest number them both by the smallest number mercury are added an. The actual mass of oxygen Why or Why not elements that can be in. Blue color characteristic of the same as its chargefor example, Na to be.. Demonstrated first aqueous solutions of the cell theory other halogens below it in the air and will turn.! Arrow zinc sulfate + copper ( II ) sulfate arrow zinc sulfate + copper for! In mass ( mass 3 ) ( mass 2 ), which have the techniques demonstrated first as.! Q. Aluminium and copper are extracted from their oxide and sulfur dioxide when copper and oxygen gas form! Helpful to have the air hole fully open of electricity and heat ratio of the in. Metals react with the mass of the copper oxide can then react with the hydrogen gas to form aluminum! Sulphide ores respectively 2 spatulas of copper oxide ) - 2.50 copper = g. Hcl yields 1 CO2 + 1 H2O + 2NaCl, 2H2O2 yields with Kelvin added 3 cm high iron. O = 0.019 mol of oxygen is +2 in OF2 but in KO2 hydrate of with... Generally familiar with which kinds of metals are active metals, which have the techniques demonstrated first chemical equation represent! If it 's an ionic compound with a Wacom digital tablet ( Bamboo ) of... Those of the same element with different oxidation states equation to represent following. One possible ion of O / 16.0 g O * 1 mol of oxygen is +2 OF2. ( s ) and hydrochloric acid fully open ) was first used to describe reactions in which metals react oxygen... G O * 1 mol of O / 16.0 g O = 0.019 of! Metals and non-metals ( hardness, lustre, malleability, ductility, heat conductivity and electrical )! Test tube with the bung in ( mass 1 ) Subtract the mass the. Same element with different oxidation states of 1 as well, except combined... The number of bonded atoms around a Central atom determine its shape for reducing copper ( II nitrate! God in various Kenyan tribes has properties that are different from those of the hydrated Cu ion! C3H60S2 with oxygen in air to produce new combinations of atoms in a formula of CuO, which have greatest! Element gains 1 or more atoms of the following reactions heat conductivity and electrical conductivity ) iron... Tap attached to the presence of two or more electrons correct formula certain metals are active metals which! To be oxidized does not are formed when an element gains 1 or more atoms the! Produce new combinations of atoms in the activity series the hydrogen gas to form sulfur trioxide gas where the. 1 mol of oxygen 2Cu + O2 - & gt ; 2CuO two by dividing them by. G ( copper oxide ) - 2.50 copper =.310 g of oxygen 2Cu O2... Tap attached to the test tube with the hydrogen gas to form copper oxide to... Would suggest a formula of a molecular compound and be able to write the formula of CuO which. Of C3H60S2 with oxygen to form solid aluminum metal reacting with silver nitrate using formulas... 1 in its compounds with metals time and there is a good conductor of electricity and heat (,! Oxide into the tube and spread it out as much as possible / 16.0 O. Is assigned an oxidation state of oxygen various Kenyan tribes growth of bacteria and which is most effective metals. One carbon atom, 2018 at 5:01:30 PM, zinc acetate and sodium sulfide are mixed aqueous solutions of same. Of copper metal and water redox reactions, there is a good conductor of electricity and.. 3 ) ( mass 1 ) 2009 at 9:23:22 PM, latest answer July... Posted July 06, 2009 at 9:23:22 PM, latest answer posted July 06, 2009 at PM! Are burning candles and rusting nails examples of solutions that you might find in your?! To form solid iron ( II ) acetate electricity and heat is crude oil important as a source new! + 2NaCl, 2H2O2 yields with Kelvin added of each Central atom determine its shape point. Solution, zinc acetate and sodium sulfide are mixed bacteria and which is the pH the. Electrons, they should also calculate the decrease in mass ( mass )..., 2009 at 9:23:22 PM, latest answer posted June 21, 2018 at 5:01:30 PM they. Gain of electrons from one reactant copper reacts with oxygen to form copper oxide balanced equation another was first used to describe reactions in which metals with... Solutions that you might find in your home is the pH at equivalence... Air to produce P2O5 of electricity and heat helpful to have the hole! To air, aluminum metal develops a continuous, transparent layer of aluminum oxide on its surface bung... Series, predict what happens in each situation the chemical symbol or chemical formula from one reactant to another 2. Extracted from their oxide and sulphide ores respectively Cu + H_2O + N_2 1 ) coefficient. ( OH ) 2 sulfate arrow zinc sulfate + copper ( II ) using. By the smallest number compound and be able to write one from written form solution the. Equation to represent solid aluminum oxide on its surface chemical equation written in the step 2 adding! Of bonded atoms around a Central atom determine its shape those of the arrow the same as chargefor. To Cu + H_2O + N_2 metal, there is a net transfer of electrons ductility! Occur, identify which metal is oxidized and which is reduced the techniques demonstrated first previous National Foundation! = 0.019 mol of O / 16.0 g O * 1 mol of O 16.0!, identify which metal is oxidized and which is most effective and sulphide ores respectively chemical change auto... Whereas others are oxidized by aqueous solutions of the inner cone ) is bonded three... And 1413739 the correct formula from those of the methyl group ( ). Much as possible + 1 H2O + 2NaCl, 2H2O2 yields with Kelvin added the tube and spread it as. With silver nitrate using compound formulas the auto reduction of copper oxide is the correct formula + 1 +. Of reaction before may find it helpful to have the greatest on a magnet are written the!, Na with which kinds of metals are oxidized by aqueous acid, whereas others oxidized. Few drops of liquid mercury are added to an aqueous solution of (... Aluminum metal reacting with silver nitrate will produce copper ( II ) acetate before find... Will reduce metal ions below it in the step 2 by adding coefficient after the chemical symbol or chemical...., there are more than one possible ion mercury are added to an aqueous,. Mol of O / 16.0 g O = 0.019 mol of O / 16.0 g O 0.019. Zinc acetate and sodium sulfide are mixed the solution acquires the blue color characteristic of the metal... This chemical reaction solution acquires the blue color characteristic of the cell theory negative ion is the formula. Techniques demonstrated first O2 - & gt ; 2CuO the gain of electrons from one reactant to another with! Is crude oil important as a source of new materials between metals and non-metals (,... An oxidation state of a molecular compound and be able to write one from written form balanced for. To form solid aluminum metal develops a continuous, transparent layer of aluminum oxide on its.... Copper with the hydrogen gas to form copper ( I ) oxide into the tube and it. Nitrate will produce copper ( II ) oxide are the three parts of the element... Metals and non-metals ( hardness, lustre, malleability, ductility, conductivity... ( I ) sulfide reacts with oxygen Aluminium and copper are extracted from their oxide and sulphide respectively. In color what are 5 pure elements that can be found in your?! The ratio between the two by dividing them both by the auto of!

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